REDUCTION OF AROMATIC AND ALIPHATIC NITRO COMPOUNDS BY SODIUM HYDROGEN TELLURIDE
نویسندگان
چکیده
منابع مشابه
Decomposition mechanisms of trinitroalkyl compounds: a theoretical study from aliphatic to aromatic nitro compounds.
The chemical mechanisms involved in the decomposition of trinitroethyl compounds were studied for both aliphatic and aromatic derivatives using density functional theory calculations. At first, in the case of 1,1,1-trinitrobutane, used as a reference molecule, two primary channels were highlighted among the five investigated ones: the breaking of the C-N bond and the HONO elimination. Then, the...
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Selective and rapid reductLon of nitro compounds is still area of considerable synthetic interestl, particularly when a molecule has several other reducible moieties. Numerous new reagents*-l4 have been developed for reduction of aromatic nitro compounds, however little attention has been paid to the reduction of aliphatic nitro compound&ry,S, which are traditionally reduced by high pressure ca...
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This work describes QSAR and SAR studies on the reduction of 27 aromatic nitro compounds by xanthine oxidase using both distance-based topological indices and quantum molecular descriptors along with indicator parameters. The application of a multiple linear regression analysis indicated that a combination of distance-based topological indices with the ad hoc molecular descriptors and the indic...
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To improve the activities of non-noble metal catalysts is highly desirable and valuable to the reduced use of noble metal resources. In this work, the supported nickel (Ni) and nickel-platinum (NiPt) nanocatalysts were derived from a layered double hydroxide/carbon composite precursor. The catalysts were characterized and the role of Pt was analysed using X-ray diffraction (XRD), high-resolutio...
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ژورنال
عنوان ژورنال: Chemistry Letters
سال: 1983
ISSN: 0366-7022,1348-0715
DOI: 10.1246/cl.1983.1373